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mankhwala

Benzidine(CAS#92-87-5)

Chemical Property:

Molecular Formula Chithunzi cha C12H12N2
Molar Misa 184.24
Kuchulukana 1.25
Melting Point 127-128 ° C
Boling Point 402 ° C
Pophulikira 11°C
Kusungunuka kwamadzi Zosungunuka pang'ono. <0.1 g/100 mL pa 22 ºC
Kusungunuka Zosungunuka mu ethanol (US EPA, 1985) ndi ether (1 g/50 mL) (Windholz et al., 1983)
Kuthamanga kwa Vapor Kutengera kuchuluka kwa mpweya wa 6.36 (Sims et al., 1988), kuthamanga kwa nthunzi kunawerengedwa kukhala 0.83 pa 20 °C.
Maonekedwe zaudongo
Mtundu Grayish-chikasu, crystalline ufa; zoyera kapena sltlyreddish makhiristo, ufa
Malire Owonetsera Chifukwa ndi carcinogen ndipo imayamwa mosavuta kudzera pakhungu, palibe TLV yomwe yapatsidwa. Kuwonekera kuyenera kukhala kocheperako kwambiri.Kuzindikiridwa Kansa ya Munthu (ACGIH);Human Carcinogen (MSHA); Carcinogen (O
Merck 13,1077
Mtengo wa BRN 742770
pKa 4.66 (pa 30 ℃)
Mkhalidwe Wosungira 2-8 ° C
Kukhazikika Wokhazikika. Zoyaka. Zosagwirizana ndi ma oxidizing amphamvu.
Refractive Index 1.6266 (chiyerekezo)
Zakuthupi ndi Zamankhwala ufa woyera kapena wofiira wa crystalline. Malo osungunuka 125 ℃, kuwira 400 ℃, (98.7kPa), kachulukidwe wachibale 1.250 (20/4 ℃), sungunuka mu ethanol otentha, asidi asidi ndi kuchepetsa hydrochloric acid, sungunuka pang'ono mu ether, sungunuka pang'ono m'madzi otentha, sungunuka m'madzi ozizira. Mtunduwu umakhala mdima mumlengalenga ndi kuwala. Analytical reagents nthawi zambiri benzidine hydrochloride kapena acetate ndi apamwamba solubility, ndi sulphate zambiri ntchito makampani. Benzidine acetate ndi woyera kapena pafupifupi woyera makhiristo, sungunuka m'madzi, asidi asidi ndi hydrochloric acid, ndipo ntchito monga chizindikiro [36341-27-2]. benzidine hydrochloride [531-85-1]. Benzidine sulfate ndi ufa wa crystalline woyera kapena waung'ono wonga kristalo, wosungunuka mu etha, wosungunuka pang'ono m'madzi, kuchepetsa asidi ndi mowa [21136-70-9].

Tsatanetsatane wa Zamalonda

Zolemba Zamalonda

Zizindikiro Zowopsa R45 - Angayambitse khansa
R22 - Zowopsa ngati zitamezedwa
R50/53 - Poizoni kwambiri kwa zamoyo zam'madzi, zitha kubweretsa zovuta kwanthawi yayitali m'malo am'madzi.
R52/53 - Zowononga zamoyo zam'madzi, zimatha kuyambitsa zovuta zanthawi yayitali m'malo am'madzi.
R39/23/24/25 -
R23/24/25 – Poizoni pokoka mpweya, kukhudzana ndi khungu komanso kummeza.
R11 - Yoyaka Kwambiri
R36/37/38 - Zokwiyitsa maso, kupuma komanso khungu.
R20/21/22 - Zowopsa pokoka mpweya, kukhudzana ndi khungu komanso kumeza.
R51/53 - Poizoni kwa zamoyo zam'madzi, zitha kubweretsa zovuta kwanthawi yayitali m'malo am'madzi.
R67 - Nthunzi imatha kuyambitsa kugona komanso chizungulire
Kufotokozera Zachitetezo S53 - Pewani kuwonekera - pezani malangizo apadera musanagwiritse ntchito.
S45 - Pakachitika ngozi kapena ngati simukumva bwino, funsani upangiri wachipatala nthawi yomweyo (onetsani chizindikirocho ngati kuli kotheka.)
S60 - Zinthuzi ndi chidebe chake ziyenera kutayidwa ngati zinyalala zowopsa.
S61 - Pewani kumasulidwa ku chilengedwe. Onani malangizo apadera / mapepala achitetezo.
S36/37 - Valani zovala zoyenera zodzitchinjiriza ndi magolovesi.
S16 - Khalani kutali ndi magwero oyatsira.
S7 - Sungani chidebe chotsekedwa mwamphamvu.
S36 - Valani zovala zoyenera zodzitetezera.
S26 - Mukakhudza maso, yambani nthawi yomweyo ndi madzi ambiri ndikupempha uphungu wachipatala.
Ma ID a UN UN 1885 6.1/PG 2
WGK Germany 3
Mtengo wa RTECS DC9625000
FLUKA BRAND F CODES 8
HS kodi 29215900
Kalasi Yowopsa 6.1(a)
Packing Group II
Poizoni Acute oral LD50 kwa mbewa 214 mg / kg, makoswe 309 mg / kg (yotchulidwa, RTECS, 1985).

 

Mawu Oyamba

Benzidine (wotchedwanso diphenylamine) ndi organic pawiri. Zotsatirazi ndizofotokozera za chikhalidwe chake, kugwiritsa ntchito, njira zopangira ndi chitetezo:

 

Ubwino:

- Maonekedwe: Benzidine ndi yoyera mpaka yopepuka yachikasu yolimba.

- Kusungunuka: kosasungunuka m'madzi, kusungunuka mu zosungunulira organic monga ma alcohols, ethers, ndi zina.

- Chizindikiro: Ndi electrophile yomwe ili ndi mawonekedwe a electrophilic substitution reaction.

 

Gwiritsani ntchito:

- Benzidine chimagwiritsidwa ntchito m'munda wa kaphatikizidwe organic. Itha kugwiritsidwa ntchito ngati zopangira komanso zopangira mankhwala monga utoto, utoto, mapulasitiki, ndi zina.

 

Njira:

- Benzidine amakonzedwa mwachizolowezi ndi kuchepetsa dinitrobiphenyl, kuchotsedwa kwa ma radiation a haloaniline, etc.

- Njira zamakono zokonzekera zimaphatikizapo kaphatikizidwe ka organic ka amines onunkhira, monga momwe gawo lapansi la diphenyl ether limathandizira ndi amino alkanes.

 

Zambiri Zachitetezo:

- Benzidine ndi poizoni ndipo angayambitse mkwiyo ndi kuwonongeka kwa thupi la munthu.

- Pogwira benzidine, chisamaliro chiyenera kutengedwa kuti pasakhale kukhudzana ndi khungu ndi kupuma, komanso zipangizo zodzitetezera monga magolovesi, magalasi otetezera, ndi masks otetezera ayenera kuvala ngati kuli kofunikira.

- Benzidine ikakhudza khungu kapena maso, iyenera kutsukidwa nthawi yomweyo ndi madzi ambiri.

- Mukasunga ndikugwiritsa ntchito benzidine, samalani kuti musakhudze zinthu zachilengedwe ndi ma oxidants kuti mupewe moto kapena kuphulika.

 


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