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mankhwala

Nitrobenzene(CAS#98-95-3)

Chemical Property:

Molecular Formula C6H5NO2
Molar Misa 123.11
Kuchulukana 1.196 g/mL pa 25 °C (kuyatsa)
Melting Point 5-6 °C (kuyatsa)
Boling Point 210-211 °C (kuyatsa)
Pophulikira 190 ° F
Kusungunuka kwamadzi pang'ono sungunuka
Kusungunuka 1.90g/l
Kuthamanga kwa Vapor 0.15 mm Hg (20 °C)
Kuchuluka kwa Vapor 4.2 (vs mpweya)
Maonekedwe Madzi
Mtundu Yellow yoyera
Malire Owonetsera TLV-TWA 1 ppm (~5 mg/m3) (ACGIH,MSHA, ndi OSHA); IDLH 200 ppm(NIOSH).
Merck 14,6588
Mtengo wa BRN 507540
pKa 3.98 (pa 0 ℃)
PH 8.1 (1g/l, H2O, 20℃)
Mkhalidwe Wosungira Sungani pansi +30 ° C.
Kukhazikika Wokhazikika. Zosagwirizana ndi ma oxidizing amphamvu, ochepetsera amphamvu, maziko amphamvu. Zoyaka. Dziwani malire a kuphulika kwakukulu.
Zophulika Malire 1.8-40% (V)
Refractive Index n20/D 1.551(lit.)
Zakuthupi ndi Zamankhwala Chovala choyera chimakhala chopanda utoto mpaka chopepuka chamafuta achikasu.
malo osungunuka 5.85 ℃
kutentha kwa 210.9 ℃
kachulukidwe wachibale 1.2037
refractive index 1.55296
flash point 88 ℃
sungunuka mu Mowa, etha ndi benzene, sungunuka pang'ono m'madzi.
Pure product ndi mafuta amadzimadzi opanda mtundu mpaka otumbululuka. Kusungunuka mu ethanol, ether ndi benzene, sungunuka m'madzi.
Gwiritsani ntchito Nitrobenzene ndi gawo lofunikira lapakati pake. Nitrobenzene anali sulfonated ndi sulfure trioxide kupeza m-nitrobenzene sulfonic acid. Itha kugwiritsidwa ntchito ngati utoto wapakatikati, wofatsa oxidant ndi anti-dye mchere s. Nitrobenzene anali sulfonated ndi chlorosulfonic asidi kupeza m-nitrobenzenesulfonyl kolorayidi, amene ankagwiritsidwa ntchito ngati wapakatikati utoto, mankhwala ndi zina zotero. Nitrobenzene amapangidwa ndi chlorine ku M-nitrochlorobenzene, yomwe imagwiritsidwa ntchito kwambiri popanga utoto ndi mankhwala ophera tizilombo. Pambuyo pochepetsa, M-chloroaniline imatha kupezeka. Ntchito ngati utoto lalanje GC, ndi mankhwala, mankhwala, fulorosenti whitening wothandizira, organic pigment intermediates. Nitrobenzene re-nitration ikhoza kukhala m-dinitrobenzene, pochepetsa ikhoza kukhala m-phenylenediamine, yogwiritsidwa ntchito ngati zopangira utoto, epoxy resin curing agent, petroleum additives, Cement accelerator, M-dinitrobenzene monga sodium sulfide mbali inanso mfundo ya M-nitroaniline. Kwa utoto lalanje maziko R, ndi wapakatikati wa azo utoto ndi organic pigment.

Tsatanetsatane wa Zamalonda

Zolemba Zamalonda

Zizindikiro Zowopsa R23/24/25 – Poizoni pokoka mpweya, kukhudzana ndi khungu komanso kummeza.
R40 - Umboni wochepa wa zotsatira za carcinogenic
R48/23/24 -
R51/53 - Poizoni kwa zamoyo zam'madzi, zitha kubweretsa zovuta kwanthawi yayitali m'malo am'madzi.
R62 - Chiwopsezo chotheka cha kusokonekera kwa chonde
R39/23/24/25 -
R11 - Yoyaka Kwambiri
R36/37/38 - Zokwiyitsa maso, kupuma komanso khungu.
R60 - Itha kuwononga chonde
R52/53 - Zowononga zamoyo zam'madzi, zimatha kuyambitsa zovuta zanthawi yayitali m'malo am'madzi.
R48/23/24/25 -
R36 - Zokhumudwitsa m'maso
R20/21/22 - Zowopsa pokoka mpweya, kukhudzana ndi khungu komanso kumeza.
Kufotokozera Zachitetezo S28 - Mukakhudza khungu, sambani nthawi yomweyo ndi sopo wambiri.
S36/37 - Valani zovala zoyenera zodzitchinjiriza ndi magolovesi.
S45 - Pakachitika ngozi kapena ngati simukumva bwino, funsani upangiri wachipatala nthawi yomweyo (onetsani chizindikirocho ngati kuli kotheka.)
S61 - Pewani kumasulidwa ku chilengedwe. Onani malangizo apadera / mapepala achitetezo.
S28A -
S16 - Khalani kutali ndi magwero oyatsira.
S7 - Sungani chidebe chotsekedwa mwamphamvu.
S27 - Chotsani nthawi yomweyo zovala zonse zowonongeka.
S53 - Pewani kuwonekera - pezani malangizo apadera musanagwiritse ntchito.
S26 - Mukakhudza maso, yambani nthawi yomweyo ndi madzi ambiri ndikupempha uphungu wachipatala.
Ma ID a UN UN 1662 6.1/PG 2
WGK Germany 2
Mtengo wa RTECS DA6475000
TSCA Inde
HS kodi 29042010
Kalasi Yowopsa 6.1
Packing Group II
Poizoni LD50 pamlomo makoswe: 600 mg/kg (PB91-108398)

 

Mawu Oyamba

Nitrobenzene) ndi mankhwala omwe amatha kukhala oyera a crystalline olimba kapena madzi achikasu okhala ndi fungo lapadera. Zotsatirazi ndikuyambitsa zina mwazinthu, ntchito, njira zokonzekera ndi chidziwitso chachitetezo cha nitrobenzene:

 

Ubwino:

Nitrobenzene sasungunuka m'madzi koma amasungunuka mu zosungunulira monga ma alcohols ndi ethers.

Itha kupezedwa ndi nitrating benzene, yomwe imapangidwa pochita benzene yokhala ndi nitric acid.

Nitrobenzene ndi chinthu chokhazikika, koma chimakhalanso chophulika ndipo chimakhala chotentha kwambiri.

 

Gwiritsani ntchito:

Nitrobenzene ndi mankhwala ofunikira ndipo amagwiritsidwa ntchito kwambiri popanga organic synthesis.

Nitrobenzene itha kugwiritsidwanso ntchito ngati chowonjezera mu zosungunulira, utoto ndi zokutira.

 

Njira:

Njira yokonzekera nitrobenzene imapezeka makamaka ndi nitrification reaction ya benzene. Mu labotale, benzene akhoza kusakaniza ndi chigawo cha nitric acid ndi sulfuric acid, yosonkhezera kutentha pang'ono, ndiyeno nkuchapitsidwa ndi madzi ozizira kuti mupeze nitrobenzene.

 

Zambiri Zachitetezo:

Nitrobenzene ndi poizoni, ndipo kukhudzana ndi kapena kupuma mpweya wake kungayambitse kuwonongeka kwa thupi.

Ndi chinthu choyaka komanso kuphulika ndipo sayenera kukhudzana ndi zoyatsira.

Zida zodzitetezera monga magolovesi ndi magalasi odzitetezera ziyenera kuvalidwa pogwira nitrobenzene, komanso malo opangira mpweya wabwino ayenera kusamalidwa.

Pakavunda kapena ngozi, njira zoyenera ziyenera kuchitidwa mwamsanga kuti ziyeretsedwe ndi kuzitaya. Tsatirani malamulo ndi malamulo oyenera kutaya zinyalala zomwe zapangidwa.


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